Lime

   

Many different lime products are called by the same name, Lime. Which is needed for fresco, where is it acquired, and how is it processed?

 

What:


Use high-calcium lime putty that is at least 94% calcium for fresco construction.

Calcium carbonate is a plentiful material in nature that can be found as limestone, marble, and even sea shells. When heated at high temperatures it releases carbon dioxide and becomes a new material known as calcium oxide, which is also known as quick lime, hot lime, lump lime, and rock lime.

"Slaking" is the term used to describe the process of adding water to the calcium oxide. The combination of calcium oxide and water create an exothermic reaction that generates a lot of heat and forms a new substance known as calcium hydroxide (hydrated lime and/or pit lime). Calcium hydroxide is an essential material in buon fresco. Check out this Youtube video to see the slaking process: Lime slaking video (Youtube)  

Calcium hydroxide comes in two forms, a completely slaked putty known as pit lime and a partially slaked powder known as hydrated lime. Hydrated lime is a product of industry and has been slaked with an autoclave just past the point of exothermic reactivity so it can be handled more safely. In addition to being considerably less reactive than calcium oxide, it is more efficient to ship as hydrated lime contains far less water, which can be added to form a putty after its arrival on the job site. As lime putty ages it increases in thickness and quality. The older the better! Frescoists typically use putty that is at least two years old. Many renaissance  artists used lime that was ten years or older.

Once in contact with atmosphere, calcium hydroxide reacts with carbon dioxide in a process called carbonation that reverts the lime back to its original substance--calcium carbonate (limestone). This process forms a crystalline mesh at the surface of the wall. It is the mesh that locks pigment particles into the plaster. This crystal skin is commonly referred to as the lime crust and can be seen by striking a dry plaster wall from the side with a powerful light. The lime crust also appears at the water's surface in the sludge bucket used to clean the trowels.

In short, lime goes through a cycle: Calcium Carbonate > Calcium Oxide > Calcium Hydroxide > Calcium Carbonate.
  


A note about the differences between hydrated lime and pit lime putties:
Hydrated lime comes packaged in paper bags with pin holes. The holes allow atmosphere in and out of the bag to help reduce pressure ruptures as the bags are commonly tossed around. Due to exposure to atmosphere, older bags risk being prematurely converted (partially) to calcium carbonate. There has also been study on the differences between the two forms at the nano level. For more on this topic see the following publication:

"Variations in High-Calcium Lime Putty and Mortar Properties Resulting from the Use of Freshly-Slaked Quicklime and Commercial Dry Hydrated Lime," The Proceedings of the 2005 International Building Lime Symposium, Orlando Florida, National Lime Association, by E. F. Hansen, K. van Balen, and C. Rodriguez-Navarro. http://www.getty.edu/conservation/science/mortars/mortars_component2.html

 

 

Where:

For those near Bowling Green, KY, Hydrated Lime can be purchased locally from:
Tennessee Farmer's Cooperative (located in Springfield, TN)
phone number: (615) 384-3573 
Cheney's Hydrated Lime $7.50 per 50lbs bag

Regional/National Hydrated Lime Distributors:
Traditionally slaked Pit Lime can be purchased here:
  • The Fresco School (Traditional Slaked Lime Putty and a complete assortment of fresco-making items and materials) 

 

 

How:

Making Lime Putty from Hydrated Lime Powder:
Ideally, a fresco painter would use pit lime that has been slaked using traditional methods (see the youtube videos in this blog on slaking calcium oxide). Because of the dangers associated with burning and slaking lime (gasses and heat), we chose to use calcium hydroxide in hydrated powder form. Be sure to use Hi-calcium hydrated lime.

In addition to a mortar mixing drill, students used a scale to measure the weight of 50lbs bags to ensure the same quantity of powder is in each bucket.














lime buon fresco























Outdoor ventilation is important. In addition to using masks, we set up a fan to gently blow powder plumes away from those who were mixing the putty. You should wear long sleeves, pants, and closed-toe shoes to prevent or minimize lime contacting your skin. Improper exposure to lime can cause a number of health issues ranging from dry skin to chemical burns or poisoning. It can even shift your body's PH levels!  




 



















When possible, use freshly made hydrated lime. You can check the shipping date on the back of bag for a clue to its age. The lime was most likely shipped shortly after being manufactured. The younger the shipping date the better! Try to find hydrated lime that is less than 6 months old. You can store unused bags of hydrate in tightly wrapped plastic bags to increase its shelf life.


















Steps for mixing the lime slurry (which thickens with time into putty):

1. Add 3 gallons of distilled water to a clean empty bucket.















2. Slowly sprinkle up to 25 lbs (half the bag) of lime into water while gently mixing with the drill bit. When the mixture thickens, add a quarter of a gallon of water to thin it out. When it's all said and done you will have added a half a gallon of distilled water, leaving a quarter for topping off, and a remaining quarter that will go unused.

Weigh the bag of lime as you go to make sure that you have added the proper amount of lime (25 lbs). When finished, the consistency should be similar to a soft milkshake. The mix should cling to drill bit and slowly drip (plop) off. It will also leave a raised trail at the surface (see pic below). Also note that it takes approximately 15 minutes to make one bucket of lime putty in this manner. 

 















3. To top off the bucket, gently add a quarter gallon of distilled water to top of mixture. This inch or less layer of water will sit on top of putty and protect it from the atmosphere.

4.Date the bucket with a marker, seal it and you are done! Be sure to store it someplace that doesn't freeze.

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